Simulation studies on a rotating ring disk electrode: Effects of ionic migration with kinetic complication-disk results

In continuation to my previous work (Guha S. AIChE J. 2013;59(4):1390-1399), in this work, effects of ionic migration are evaluated for disk region of a rotating ring disk electrode system by numerically solving complex differential equations, developed for mass transfer along with kinetic complication in presence of ionic migration under limiting current condition. The system for simulation is 0.01 M Fe₂(SO₄)₃ solution with H₂SO₄ as supporting electrolyte. Simulation cases are presence and absence of ionic migration with kinetic complication (oxidation of Fe²⁺ to Fe³⁺ under O₂ pressure). Results show that concentration boundary layer thickness of reactant Fe³⁺ reduces appreciably and steady-state disk current reduces substantially in presence of migration. Simulated steady-state disk current in absence of migration case agrees well with published data. Results indicate higher Fe²⁺ concentration in presence of migration and thereby higher rate of oxidation of Fe²⁺ to Fe³⁺ at all rate constant values.     

望云煤矿15101综放面沿空煤巷围岩支护技术研究

通过现场调研和松动圈观测对望云矿15101工作面沿空煤巷0~450m段破坏进行了统计,得出沿空煤巷顶板偏向煤柱侧及煤柱帮不对称破坏的特点。根据这一特点提出采用偏向煤柱侧布置锚索及增加锚杆长度与直径和增加锚杆索数量的控制方法,在现场试验中取得良好控制效果。     

汽车同步器齿环用耐高温结构胶膜的性能研究

同步器齿环与碳纤维耐摩擦材料是通过胶粘剂实现粘接,而胶粘剂耐高温性能的优劣则是决定其使用寿命的决定性因素。本文研究了环氧树脂E-51体系、环氧树脂AG80体系以及基材表面处理工艺对于结构胶膜耐高温性能的影响,采用熔融共混法制备了胶粘剂并以玻璃纤维布为背衬制备了耐高温结构胶膜。采用高低温拉力机对不同体系制备的结构胶膜进行了常温、200℃高温的钢材搭接剪切强度的测试。结果表明,对于E-51体系,提高体系交联密度可显著增大常温剪切强度,但高温剪切强度明显下降;对于四官能度的AG80体系,AG80的用量是影响其高温性能的主要因素,同时基材表面喷砂水洗处理后可显著增大结构胶膜与基材粘接有效面积,进而显著改善高温性能。所制备的结构胶膜较常用胶粘剂使用更加便捷,耐高温性能优良,满足同步器齿环使用要求。     

综合传动装置胀圈密封轴槽间隙设计方法

研究一种基于理论计算与CFD仿真的胀圈密封环轴槽间隙尺寸设计方法。基于流体力学的基本方程,建立胀圈密封流场的数学模型;结合实际工况与使用要求,确定胀圈密封环与轴槽径向间隙、轴向间隙及配流衬套与旋转轴之间的间隙尺寸的约束范围;建立流场的计算流体力学模型,通过正交试验设计,分析影响胀圈密封性能的高灵敏度因素;以密封泄漏量最小为目标函数,选取最佳的轴槽间隙设计参数。结果表明,研究的3种间隙中,相比于胀圈密封环与轴槽的径向间隙、轴向间隙,配流衬套与旋转轴之间的间隙对密封环的泄漏量影响更为显著,当配流衬套与旋转轴之间的间隙增大,泄漏量也随之增大。     

膨胀剂对约束条件下UHPC早期抗裂性能影响的试验研究

超高性能混凝土(UHPC)在钢桥面铺装结构中由于铺装材料受到钢板、栓钉等的约束,加上材料本身水胶比小,更易收缩,早期容易承受拉应力导致开裂。通过在拌和过程中添加膨胀剂可以起到减小收缩的作用,但该方法对于约束条件下的UHPC铺装的早期抗裂性能提升是否有促进作用,仍需通过更多试验进行合理评估和深入研究。通过圆环法对3组不同配方的UHPC在均匀约束条件下的早期抗裂性能进行定量测试,并将试验数据进行回归分析和计算,得到了各组的平均应力发展速率,进而评估了各组的开裂风险等级。试验结果表明,通过在UHPC中加入适量膨胀剂,可使其最终收缩应力减小,并可降低其收缩应力发展速率,进一步降低其在约束条件下的开裂风险。     

A novel proposal for all optical 3 to 8 decoder based on nonlinear ring resonators

In this paper, a 3 to 8 optical decoder was proposed using nonlinear photonic crystal ring resonators. For realizing the 3 to 8 decoder, we combined seven 1 to 2 optical decoders. In the proposed structure, X, Y and Z serve as input ports. By combination of these ports, one can control which output port to be ON. The maximum time delay of the proposed structure is about 6?ps.     

Green touch for hydrogen production via alkaline electrolysis: The semi-flexible PV panels mounted wind turbine design,production and performance analysis

The novel solar-wind integrated system has been firstly used for hydrogen production in literature with validating theoretical, simulated and experimental studies. This integrated system consists of two main parts; solar-assisted wind turbine and alkaline electrolysis cell.In the first part of this system, the semi-flexible PV panels are smoothly integrated on the vertical axis wind turbine blade. This is a unique design in literature, unlike the hybrid systems that include wind turbines and solar PV panels in published literature. The production and testing of the hybrid integrated system in a single structure were performed both in laboratory conditions and also the system was set up the roof of ATU (Adana Alparslan Turkes Science and Technology University) in Adana. The second part includes hydrogen production via alkaline electrolysis system. The cathodes consist of nickel-coated copper (Cu/Ni) and nickel-vanadium binary coated copper (Cu/NiV), that was produced via electrodeposition technique by self-supporting. The performance of electrodes was compared in 1 M KOH solution via I–V behavior, electrochemical impedance spectroscopy, and long term cathodic polarization analysis. Results showed that polarization resistance was decreased almost 4 times by NiV when comparing the Ni. The surface inhomogeneity values were 0.91 and 0.81 for Cu/Ni and Cu/NiV respectively. The hydrogen gas evolved at the cathodes was also measured and higher volumes were detected for NiV binary coating.     

高精度多环片自动装配控制技术

为了实现对微小环片零件的自动化装配,搭建了自动装配系统.通过4根直线导向轴与4个直线轴承来提高系统的导向精度和刚度.采用直线导轨进行各装配作业模块之间的切换,保证了微小环片零件的自动装配与取出.在环片的装配方向上,螺旋升降机和光栅尺实现环片的位置精度控制.在Lab VIEW编程环境中,采用分层软件架构和模块化控制思想,避免了不必要的数据循环检测与丢失,能够达到环片组件的装配精度要求.控制系统分为系统初始化模块、参数设置模块、装配模块和取出模块,自动装配系统通过各个模块间的相互交流配合完成装配任务.采用本文中自动装配系统装配环片的实验结果表明,环片零件装配的最大位置误差为26μm,垂直度误差为17μm,平均装配时间为75 s/片,可满足环片组件所需的精度要求.     

Synthesis and characterization of copolymers with the same proportions of polystyrene and poly(ethylene oxide) compositions but different connection sequence by the efficient Williamson reaction

The AB type diblock PS‐b‐PEO and ABA type triblock PS‐b‐PEO‐b‐PS copolymers containing the same proportions of polystyrene (PS) and poly(ethylene oxide) (PEO) but different connection sequence were synthesized and investigated. Using the sequential living anionic polymerization and ring‐opening polymerization mechanisms, diblock PS‐b‐PEO copolymers with one hydroxyl group at the PEO end were obtained. Then, using the classic and efficient Williamson reaction (realized in a ‘click’ style), triblock PS‐b‐PEO‐b‐PS copolymers were achieved by a coupling reaction between hydroxyl groups at the PEO end of PS‐b‐PEO. The PS‐b‐PEO and PS‐b‐PEO‐b‐PS copolymers were well characterized by ¹H NMR spectra and SEC measurements. The critical micelle concentration (CMC) and thermal behaviors were also investigated by steady‐state fluorescence spectra and DSC, respectively. The results showed that, because the PEO segment in triblock PS‐b‐PEO‐b‐PS was more restricted than that in diblock PS‐b‐PEO copolymer, the former PS‐b‐PEO‐b‐PS copolymer always gave higher CMC values and lower crystallization temperature (T_c), melting temperature (T_m) and degree of crystallinity (X_c) parameters. © 2015 Society of Chemical Industry